What is a mineral?
Minerals are natural compounds
formed through geological processes. The term "mineral" encompasses not only the
material's chemical composition, but also the mineral's structure. Minerals
range in composition from pure elements and simple salts to very complex
silicates with thousands of known forms (organic compounds are excluded). The
study of minerals is called mineralogy.
Mineral definition and classification
To be classified as a "true" mineral, a substance must be a solid and have a
crystal structure. It must also be an inorganic, naturally-occurring,
homogeneous substance with a defined chemical composition. The chemical
composition may vary between end members of a mineral system. For example the
plagioclase feldspars comprise a continuous series from sodium-rich albite
(NaAlSi3O8) to calcium-rich anorthite (CaAl2Si2O8) with four recognized
intermediate compositions between. Mineral-like substances that don't strictly
meet the definition are sometimes classified as mineraloids. Other
natural-occurring substances are Nonminerals. Industrial minerals is a market
term and refers to commercially valuable mined materials.
A crystal structure is the orderly geometric spatial arrangement of atoms in the
internal structure of a mineral. There are 14 basic crystal lattice arrangements
of atoms in three dimensions, and these are referred to as the 14 "Bravais
lattices". Each of these lattices can be classified into one of the six crystal
systems, and all crystal structures currently recognized fit in one Bravais
lattice and one crystal system. This crystal structure is based on regular
internal atomic or ionic arrangement that is often expressed in the geometric
form that the crystal takes. Even when the mineral grains are too small to see
or are irregularly shaped, the underlying crystal structure is always periodic,
and can be determined by X-ray diffraction.
Chemistry and crystal structure together define a mineral. In fact, two or more
minerals may have the same chemical composition, but differ in crystal structure
(these are known as polymorphs). For example, pyrite and marcasite are both iron
sulfide, but their arrangement of atoms differs. Similarly, some minerals have
different chemical compositions, but the same crystal structure: for example,
halite (made from sodium and chlorine), galena (made from lead and sulfur) and
periclase (made from magnesium and oxygen) all share the same cubic crystal
structure.
Crystal structure greatly influences a mineral's physical properties. For
example, though diamond and graphite have the same composition (both are pure
carbon), graphite is very soft, while diamond is the hardest of all known
minerals. This happens because the carbon atoms in graphite are arranged into
sheets which can slide easily past each other, while the carbon atoms in diamond
form a strong, interlocking three-dimensional network.
There are currently just over 4,000 known minerals, according to the
International Mineralogical Association, which is responsible for the approval
of and naming of new mineral species found in nature. Of these, perhaps 150 can
be called "common," 50 are "occasional," and the rest are "rare" to "extremely
rare."
Chemical properties of minerals
Minerals may be classified according to chemical composition. They are here
categorized by anion group. The list below is in approximate order of their
abundance in the Earth's crust. The list follows the Dana classification system.
Silicate class
The largest group of minerals by far are the silicates (most rocks are >95%
silicates), which are composed largely of silicon and oxygen, with the addition
of ions such as aluminium, magnesium, iron, and calcium. Some important
rock-forming silicates include the feldspars, quartz, olivines, pyroxenes,
amphiboles, garnets, and micas.
Carbonate class
The carbonate minerals consist of those minerals containing the anion (CO3)2-
and include calcite and aragonite (both calcium carbonate), dolomite
(magnesium/calcium carbonate) and siderite (iron carbonate). Carbonates are
commonly deposited in marine settings when the shells of dead planktonic life
settle and accumulate on the sea floor. Carbonates are also found in evaporitic
settings (e.g. the Great Salt Lake, Utah) and also in karst regions, where the
dissolution and reprecipitation of carbonates leads to the formation of caves,
stalactites and stalagmites. The carbonate class also includes the nitrate and
borate minerals.
Sulfate class
Sulfates all contain the sulfate anion, SO42-. Sulfates commonly form in
evaporitic settings where highly saline waters slowly evaporate, allowing the
formation of both sulfates and halides at the water-sediment interface. Sulfates
also occur in hydrothermal vein systems as gangue minerals along with sulfide
ore minerals. Another occurrence is as secondary oxidation products of original
sulfide minerals. Common sulfates include anhydrite (calcium sulfate), celestite
(strontium sulfate), barite (barium sulfate), and gypsum (hydrated calcium
sulfate). The sulfate class also includes the chromate, molybdate, selenate,
sulfite, tellurate, and tungstate minerals.
Halide class
The halides are the group of minerals forming the natural salts and include
fluorite (calcium fluoride), halite (sodium chloride), sylvite (potassium
chloride), and sal ammoniac (ammonium chloride). Halides, like sulfates, are
commonly found in evaporitic settings such as playa lakes and landlocked seas
such as the Dead Sea and Great Salt Lake. The halide class includes the
fluoride, chloride, and iodide minerals.
Oxide class
Oxides are extremely important in mining as they form many of the ores from
which valuable metals can be extracted. They also carry the best record of
changes in the Earth's magnetic field. They commonly occur as precipitates close
to the Earth's surface, oxidation products of other minerals in the near surface
weathering zone, and as accessory minerals in igneous rocks of the crust and
mantle. Common oxides include hematite (iron oxide), magnetite (iron oxide),
chromite (iron chromium oxide), spinel (magnesium aluminium oxide - a common
component of the mantle), ilmenite (iron titanium oxide), rutile (titanium
dioxide), and ice (hydrogen oxide). The oxide class includes the oxide and the
hydroxide minerals.
Sulfide class
Many sulfide minerals are economically important as metal ores. Common sulfides
include pyrite (iron sulfide - commonly known as fools' gold), chalcopyrite
(copper iron sulfide), pentlandite (nickel iron sulfide), and galena (lead
sulfide). The sulfide class also includes the selenides, the tellurides, the
arsenides, the antimonides, the bismuthinides, and the sulfosalts (sulfur and a
second anion such as arsenic).
Phosphate class
The phosphate mineral group actually includes any mineral with a tetrahedral
unit AO4 where A can be phosphorus, antimony, arsenic or vanadium. By far the
most common phosphate is apatite which is an important biological mineral found
in teeth and bones of many animals. The phosphate class includes the phosphate,
arsenate, vanadate, and antimonate minerals.
Element class
The Elemental group includes metals and intermetallic elements (gold, silver,
copper), semi-metals and non-metals (antimony, bismuth, graphite, sulfur). This
group also includes natural alloys, such as electrum (a natural alloy of gold
and silver), phosphides, silicides, nitrides and carbides (which are usually
only found naturally in a few rare meteorites).